Portal de Periódicos da CAPES

Preparation of gelatin-N-vinylpyrrolidone graft copolymer

1998; Wiley; Volume: 68; Issue: 9 Linguagem: Inglês

10.1002/(sici)1097-4628(19980531)68

1097-4628

Jianping Gao, Zhichong Li, Wei Wang, Mingzhi Huang,

Polymer Surface Interaction Studies

The graft copolymerization of N-vinylpyrrolidone (VP) onto gelatin was carried out by the following four different initiator systems: AIBN, K2S2O8, H2O2—Fe2+, and Ce4+—HNO3. The last one caused the monomer to lose the double-bond and polymerization ability due to the hydrolysis of the monomer. Using α,α-azobisisobutyronitrile as an initiator, the graft copolymerization of gelatin and N-vinylpyrrolidone in aqueous medium was studied systematically. The relationships between the rate of grafting and the concentration of initiator, monomer, and gelatin were established experimentally. Meanwhile, the rate equation was also derived from the proposed reaction mechanism, and it was similar to the equation previously obtained experimentally. The apparent activation energies for homopolymerization (Eh), graft copolymerization (Eg), and over all polymerization (Ep) were calculated. The graft efficiency and molecular weight of the grafted PVP were measured by hydrolyzing the backbone with hydrochloric acid. The graft copolymers Gel-g-PVP were added into the coating films, and the physical properties of the films, such as hardening ability, dimensional stability, and wetting property were investigated. © 1998 John Wiley & Sons, Inc. J Appl Polym Sci 68: 1485–1492, 1998