Determination of aromatics and naphthenes in straight run gasoline by 1H NMR spectroscopy. Part I
2000; Elsevier BV; Volume: 79; Issue: 9 Linguagem: Inglês
10.1016/s0016-2361(99)00238-0
ISSN1873-7153
AutoresG. S. Kapur, Ajay P. Singh, A. S. Sarpal,
Tópico(s)NMR spectroscopy and applications
ResumoA 1H NMR-based method has been developed for determining the composition (aromatics, naphthenes and paraffins) of straight run gasoline fractions. The equations required for the calculations have been derived based on the assignment of the overlapped 1H NMR spectra of the samples with particular emphasis on signals from naphthenes and iso-paraffins. The 1H NMR results have been compared with those obtained from GC method. The absolute standard deviations between the NMR and GC methods are1.7 and 2.1% for total aromatics and naphthenes, respectively.
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