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Ordering at Two Length Scales in Comb−Coil Diblock Copolymers Consisting of Only Two Different Monomers

2002; American Chemical Society; Volume: 35; Issue: 3 Linguagem: Inglês

10.1021/ma010519v

1520-5835

Rikkert J. Nap, Gerrit ten Brinke,

Advanced Polymer Synthesis and Characterization

The microphase-separated morphology of a melt of a specific class of comb−coil diblock copolymers, consisting of an AB comb block and a linear homopolymer A block, is analyzed in the weak segregation limit. On increasing the length of the homopolymer A block, the systems go through a characteristic series of structural transitions. Starting from the pure comb copolymer, the first series of structures involve a short length scale followed by structures involving a large length scale. A maximum of two critical points exists. Furthermore, in the two parameter space characterizing the comb−coil diblock copolymer molecules considered, a nontrivial bifurcation point exists beyond which the structure factor can have two maxima (two correlation hole peaks).