Spin Densities in Dimesitylmethyl
1960; American Institute of Physics; Volume: 32; Issue: 5 Linguagem: Inglês
10.1063/1.1730946
ISSN1520-9032
Autores Tópico(s)Chemical Reactions and Mechanisms
ResumoA simple valence bond calculation indicates that if the dimesitylmethyl radical were planar large unpaired spin densities would appear on the ring methyl groups giving a spectrum about 130 gauss wide. A perturbation calculation, assuming that the molecule is very twisted, gives spin densities ρ1=1.000, ρ2=—0.069, ρ3=0.054, ρ4=—0.040, ρ5=0.043 on the carbon atoms, numbered from the center outwards.
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