Controlling the stereoselectivity of rac-LA polymerization by chiral recognition induced the formation of homochiral dimeric metal alkoxides
2016; Royal Society of Chemistry; Volume: 7; Issue: 11 Linguagem: Inglês
10.1039/c5py02005k
ISSN1759-9962
AutoresPaweł Horeglad, Martyna Cybularczyk‐Cecotka, A. Litwińska, Anna Maria Dąbrowska, Maciej Dranka, Grażyna Z. Żukowska, Mateusz Urbańczyk, Michał Michalak,
Tópico(s)Polyoxometalates: Synthesis and Applications
ResumoChiral recognition of monomeric Me 2 MOR units resulting in the formation of homochiral dimeric species [Me 2 M(μ-OR)] 2 (M = Ga, In), leads to heteroselective catalysts for the ring opening polymerization of rac -lactide ( rac -LA).
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