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Rapid Synthesis of Cobalt Nitride Nanowires: Highly Efficient and Low‐Cost Catalysts for Oxygen Evolution

2016; Wiley; Volume: 55; Issue: 30 Linguagem: Inglês

10.1002/anie.201604372

1521-3773

Yongqi Zhang, Bo Ouyang, Jing Xu, Guichong Jia, Shi Chen, Rajdeep Singh Rawat, Hong Jin Fan,

Fuel Cells and Related Materials

Abstract Electrochemical splitting of water to produce hydrogen and oxygen is an important process for many energy storage and conversion devices. Developing efficient, durable, low‐cost, and earth‐abundant electrocatalysts for the oxygen evolution reaction (OER) is of great urgency. To achieve the rapid synthesis of transition‐metal nitride nanostructures and improve their electrocatalytic performance, a new strategy has been developed to convert cobalt oxide precursors into cobalt nitride nanowires through N 2 radio frequency plasma treatment. This method requires significantly shorter reaction times (about 1 min) at room temperature compared to conventional high‐temperature NH 3 annealing which requires a few hours. The plasma treatment significantly enhances the OER activity, as evidenced by a low overpotential of 290 mV to reach a current density of 10 mA cm −2 , a small Tafel slope, and long‐term durability in an alkaline electrolyte.