A simple preparation of iodoarenes, iodoalkenes and iodoalkynes by reaction of organolithiums with 2,2,2-trifluoro-1-iodoethane
1999; Elsevier BV; Volume: 40; Issue: 36 Linguagem: Inglês
10.1016/s0040-4039(99)01343-x
ISSN1873-3581
AutoresI.J. Blackmore, Andrew N. Boa, Ernest J. Murray, Michael Robert Dennis, Simon Woodward,
Tópico(s)Synthesis and Reactions of Organic Compounds
ResumoOrganolithium anions, generated either by deprotonation or lithium-bromine exchange, when quenched with 2,2,2-trifluoro-1-iodoethane produce cleanly the synthetically useful iodoarenes, iodoalkenes and iodoalkynes.
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