Artigo Revisado por pares

Alcohol-alcohol cross-coupling enabled by S H 2 radical sorting

2024; American Association for the Advancement of Science; Volume: 383; Issue: 6689 Linguagem: Inglês

10.1126/science.adl5890

ISSN

1095-9203

Autores

Ruizhe Chen, Nicholas E. Intermaggio, Jiaxin Xie, James A. Rossi‐Ashton, Colin A. Gould, Robert T. Martin, Jesús Alcázar, David W. C. MacMillan,

Tópico(s)

Sulfur-Based Synthesis Techniques

Resumo

Alcohols represent a functional group class with unparalleled abundance and structural diversity. In an era of chemical synthesis that prioritizes reducing time to target and maximizing exploration of chemical space, harnessing these building blocks for carbon-carbon bond-forming reactions is a key goal in organic chemistry. In particular, leveraging a single activation mode to form a new C(sp

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