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Adsorption-catalysis synergy in the visible-light-driven removal of 17β-estradiol by (Au)TiO2 nanotubes-graphene composites

2024; Elsevier BV; Volume: 12; Issue: 3 Linguagem: Inglês

10.1016/j.jece.2024.112885

2213-3437

Dragoș-Viorel Cosma, Marcela‐Corina Roşu, Crina Socaci, Arpad Mihai Rostas, Alexandra Urda, Teodora Radu, Alexandru Turza, Monica Dan, Ruxandra M. Costescu, Kim Robert Gustavsen, Oleksandr Dobroliubov, Kaiying Wang,

Carbon and Quantum Dots Applications

Visible light-mediated photodegradation offers a sustainable and environmentally friendly solution for removing emerging contaminants from water sources. Herein, we report on the synergy effect between adsorption and visible-light-driven photo-degradation of 17β-estradiol using (Au)TiO2 nanotubes-graphene composites. The graphene structures (graphene oxide - GO or thermally reduced graphene oxide - trGO) provide a platform for strong adsorption of 17β-estradiol molecules and facilitate the charge transfer between plasmonic Au nanoparticles and TiO2, leading to an improvement of the overall degradation process. To better understand the effect of Au nanoparticles and TiO2 separately, three different concentrations of Au (1%, 2.5%, and 5%) were prepared and characterized. The estrogenic molecules preferred GO over trGO, suggesting that hydrogen bonds govern the interaction between GO and 17β-estradiol. Consequently, a higher photocatalytic efficiency of GO-containing composites was observed when removing estrogenic molecules. The role of adsorption proved crucial for capturing and retaining more contaminant molecules on the composite surface, thus increasing the odds of surface reactions with the photogenerated carriers. A total removal of 17β-estradiol has been obtained for Au (1%, 2.5%, and 5%) TiO2 nanotubes-GO. The mechanism behind the adsorption and photo-degradation processes has been discussed.