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Artigo Revisado por pares

Zsófia E. Blastik, S. Voltrová, Václav Matoušek, Bronislav Jurásek, David W. Manley, Blanka Klepetářová, Petr Beier,

Abstract We report an efficient and scalable synthesis of azidotrifluoromethane (CF 3 N 3 ) and longer perfluorocarbon‐chain analogues (R F N 3 ; R F =C 2 F 5 , n C 3 F 7 , n C 8 F 17 ), which enables the direct insertion of CF 3 and perfluoroalkyl groups into triazole ring systems. The azidoperfluoroalkanes show good reactivity with terminal alkynes in copper(I)‐catalyzed azide–alkyne cycloaddition (CuAAC), giving access to rare and stable N ‐perfluoroalkyl triazoles. Azidoperfluoroalkanes are thermally stable ...

Tópico(s): Cyclopropane Reaction Mechanisms

2016 - Wiley | Angewandte Chemie International Edition

Artigo Revisado por pares

Zsófia E. Blastik, S. Voltrová, Václav Matoušek, Bronislav Jurásek, David W. Manley, Blanka Klepetářová, Petr Beier,

Abstract We report an efficient and scalable synthesis of azidotrifluoromethane (CF 3 N 3 ) and longer perfluorocarbon‐chain analogues (R F N 3 ; R F =C 2 F 5 , n C 3 F 7 , n C 8 F 17 ), which enables the direct insertion of CF 3 and perfluoroalkyl groups into triazole ring systems. The azidoperfluoroalkanes show good reactivity with terminal alkynes in copper(I)‐catalyzed azide–alkyne cycloaddition (CuAAC), giving access to rare and stable N ‐perfluoroalkyl triazoles. Azidoperfluoroalkanes are thermally stable ...

Tópico(s): Cyclopropane Reaction Mechanisms

2016 - Wiley | Angewandte Chemie

Artigo Revisado por pares

Michal Jurášek, Petr Džubák, David Sedlák, Hana Dvořáková, Marián Hajdúch, Petr Bartůněk, Pavel Drašar,

There were synthesized new types of ribbon type steroidal dimers derived from three types of steroidal skeletons (cholic acid, etienic acid, estrone) using CuI catalyzed 1, 3-dipolar cycloaddition reaction. Steroid parts of the molecular "ribbons" are linked by heterocyclic moiety, namely by 2,6-bis((1H-1,2,3-triazol-1-yl)-methyl)pyridine. Compounds synthesized possess different cytotoxic and hormone receptor modulating activities.

Tópico(s): Synthesis of β-Lactam Compounds

2013 - Elsevier BV | Steroids

Artigo Acesso aberto Revisado por pares

Geoffrey A. R. Nobes, L. Jurášek, R. H. Marchessault, David P. Martin, Jean Luc Putaux, H. Chanzy,

Transmission electron microscopy (TEM) and Cryo-TEM were used to study the growth kinetics of poly(3-hydroxybutyrate) granules produced by in vitro polymerization. The in vitro formation of poly(3-hydroxybutyrate) uses a recombinant form of the PHA synthase to polymerize [R]-(–)-3-hydroxybutyryl-CoA. Since the in vitro reaction contains only synthase and monomer, it is a simpler system than the in vivo biosynthesis of poly(3-hydroxybutyrate). TEM and Cryo-TEM were used in conjunction with image analysis ...

Tópico(s): Biofuel production and bioconversion

2000 - Wiley | Macromolecular Rapid Communications

Artigo Revisado por pares

R. Kada, Jaroslav Kováč, A. JURASEK, L Osborn David,

Tópico(s): Synthesis and Reactivity of Sulfur-Containing Compounds

1973 - Wiley-VCH | Collection of Czechoslovak Chemical Communications

Artigo Revisado por pares

Vladimíra Svobodová Pavlíčková, Michal Jurášek, Silvie Rimpelová, Кamil Záruba, David Sedlák, M Simková, David Kodr, Eliška Staňková, Jan Fähnrich, Zdeňka Rottnerová, Petr Bartůněk, Oldřich Lapčı́k, Pavel Drašar, Tomáš Ruml,

Nandrolone–pheophorbide a fluorescent conjugate exhibiting promising potential in targeting of androgen receptor-positive cancer cells and their destruction by photodynamic therapy.

Tópico(s): Porphyrin and Phthalocyanine Chemistry

2019 - Royal Society of Chemistry | Journal of Materials Chemistry B

Artigo Revisado por pares

Kateřina Hájková, Bronislav Jurásek, Jan Čejka, Kristýna Štefková, Tomáš Páleníček, David Sýkora, Martin Kuchař,

Abstract Deschloroketamine (2‐(methylamino)‐2‐phenyl‐cyclohexanone) is a ketamine analog belonging to a group of dissociative anesthetics, which have been distributed within the illicit market since 2015. However, it was also being sold as ‘ketamine' misleading people to believe that they were getting genuine ketamine. Dissociative anesthetics have also come to the attention of the psychiatric field due to their potential properties in the treatment of depression. At present, there is a dearth of ...

Tópico(s): Analytical Chemistry and Chromatography

2019 - Wiley | Drug Testing and Analysis

Artigo Acesso aberto Revisado por pares

Magdaléna Vágnerová, Natalie Kolderova, Bronislav Jurásek, David Sýkora, Martin Kuchař,

Methoxphenidine (MXP) is new psychoactive substance belonging to the group of dissociative anesthetics. It appeared on the black market in 2013, and MXP intoxications have been reported with at least three deaths since then. To understanding the mechanism of toxicity and effects of MXP, it is important to know its pharmacological properties (e.g. toxicity, activity on receptors and ADME) and metabolism which may be further exploited to study its mechanism of action in vivo. Metabolism of such compound ...

Tópico(s): Analytical Chemistry and Chromatography

2022 - Elsevier BV | Annales de Toxicologie Analytique

Artigo Revisado por pares

Michal Jurášek, Markéta Schmidt Černohorská, Jiřı́ Řehulka, Vojtěch Spiwok, Tetyana Sulimenko, Eduarda Dráberová, Maria Darmostuk, Soňa Gurská, Ivo Frydrych, Renata Buriánová, Tomáš Ruml, Marián Hajdúch, Petr Bartůněk, Pavel Dráber, Petr Džubák, Pavel Drašar, David Sedlák,

Microtubule dynamics is one of the major targets for new chemotherapeutic agents. This communication presents the synthesis and biological profiling of steroidal dimers based on estradiol, testosterone and pregnenolone bridged by 2,6-bis(azidomethyl)pyridine between D rings. The biological profiling revealed unique properties of the estradiol dimer including cytotoxic activities on a panel of 11 human cell lines, ability to arrest in the G2/M phase of the cell cycle accompanied with the attenuation ...

Tópico(s): Cancer therapeutics and mechanisms

2018 - Elsevier BV | The Journal of Steroid Biochemistry and Molecular Biology

Artigo

R. Kada, Jaroslav Kováč, A. JURASEK, L. Dávid,

Abstract Bei der Kondensation der Phenylendiamine (I) mit den Furfuralen (II) in Nitrobenzol oder in wäßrigem Äthanol in Gegenwart von Cu(II)‐acetat bilden sich primär die jeweiligen Schiffschen Basen, die sich unter den Reaktionsbedingungen zu den entsprechenden Furylbenzimidazolen (III) cyclisieren.

Tópico(s): Synthesis and Reactions of Organic Compounds

1973 - Wiley | Chemischer Informationsdienst

Artigo Acesso aberto Revisado por pares

Kateřina Trková, David Sumerauer, Adéla Bubeníková, Lenka Krsková, Aleš Vícha, Miroslav Koblížek, Josef Zámečnı́k, Bruno Jurasek, Martin Kynčl, Běla Malinová, Barbora Ondrová, David Jones, Martin Sill, Martina Strnadová, Lucie Stolova, Adéla Mišove, Vladimír Beneš, Michal Zápotocký,

Abstract In this study, we provide a comprehensive clinical and molecular biological characterization of radiation-induced gliomas (RIG), including a risk assessment for developing gliomas. A cohort of 12 patients who developed RIG 9.5 years (3–31 years) after previous cranial radiotherapy for brain tumors or T-cell acute lymphoblastic leukemia was established. The derived risk of RIG development based on our consecutive cohort of 371 irradiated patients was 1.6% at 10 years and 3.02% at 15 years. ...

Tópico(s): Cancer, Hypoxia, and Metabolism

2024 - Nature Portfolio | Scientific Reports

Artigo Acesso aberto Revisado por pares

Mustafa A. Salih, Thomas M. Bosley, Ibrahim A. Alorainy, Mohamed M. Sabry, Mohamed Hashed, Eiman A. Al-Yamani, Siham El-Akoum, Sarar Mohamed, Khaled K. Abu‐Amero, A. Hellani, Ana M. Saldarriaga Cartagena, Ananda S. Prasad, Mark Rupar, M. Strong, Nancy C. Tuchman, Charlotte Mew, Suvasini Sharma, Asuri N. Prasad, Michael D. Hill, Carol Kenney, Imanuel Dzialowski, Jean-Martin Boulanger, Andrew M. Demchuk, Philip A. Barber, Timothy Watson, Nicolas U. Weir, Alastair Buchanfor, Katherine Nichols, David Fam, Cheryl Cook, Michelle Pearce, Gail Elliot, Sylvia Baago, Kenneth Rockwood, Tiffany W. Chow, Lawrence Korngut, Angela Genge, Margaret Johnston, Timothy Benstead, Pierre R. Bourque, Hannah Briemberg, Ashley Casey, N 'amour, Daniele Theseider Dupré, W Figlewicz, Walter Hader, Scott Johnston, Manas Kalra, C Melanson, Giuliana Cattelan O'Connell, Christopher M. Rouleau, John Baldwin Shoesmith, Lionel Wee, Ji Hong Kim, Jinyoung Youn, Hyeeun Shin, Jin Cho, Cynthia Gagnon, Maud‐Christine Chouinard, Luc Laberge, Diane Brisson, Daniel Gaudet, Mélissa Lavoie, Nadine Leclerc, J.P. MATHIEU, Depth Electrodes, In Pediatric, Epilepsy Surgery, Janani Kassiri, Sharon Jeffpugh, Laura Car Line, Thomas Jurasek, Matt Snyder, David Wheatley, Sirajeddin Belkhair, Gwynedd E. Pickett, Thiffault, Marie‐Josée Dicaire, Martine Tétreault, Kjv Huang, Julie Demers-Lamarche, Gordon R. Bernard, Antoine Duquette, R Lariviire, Kalle Gehring, Alexandre Montpetit, Peter S. McPherson, A Richter, Neil J. Mitchell, C Dupre, Jean‐Briac Prévost, J.P. Bouchard, James Marriott, Muhammad Mamdani, Gustavo Saposnik, Tara Gomes, Michael Manno, Paul O’Connor, Chun‐Hong Shen, Yi Guo, Wei Luo, Lin Chen, Meiping Ding, Tian Xu, Jintao Zhang, Tan Xu, Wenqing Liu, Yan Kong, Yonghong Zhang, Fahd Alsufiani, Jorge G. Burneo, Richard S. McLachlan, David M. Pelz, David A. Steven, Robert Hammond,

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2013 - Cambridge University Press | Canadian Journal of Neurological Sciences / Journal Canadien des Sciences Neurologiques

Artigo Acesso aberto Revisado por pares

David Kodr, Jarmila Stanková, Michaela Rumlová, Petr Džubák, Jiřı́ Řehulka, Tomáš Zimmermann, Ivana Křížová, Soňa Gurská, Marián Hajdúch, Pavel Drašar, Michal Jurášek,

Betulinic acid (BA) is a potent triterpene, which has shown promising potential in cancer and HIV-1 treatment. Here, we report a synthesis and biological evaluation of 17 new compounds, including BODIPY labelled analogues derived from BA. The analogues terminated by amino moiety showed increased cytotoxicity (e.g., BA had on CCRF-CEM IC50 > 50 μM, amine 3 IC50 0.21 and amine 14 IC50 0.29). The cell-cycle arrest was evaluated and did not show general features for all the tested compounds. A fluorescence ...

Tópico(s): Phytochemical compounds biological activities

2021 - Multidisciplinary Digital Publishing Institute | Biomedicines

Artigo Revisado por pares

DIANE W. BIRCKBICHLER,

... CORL, KATHRYN A., BARBARA S. JURASEK & RICHARD T. JURASEK. Sprechen wir Deutsch! Prosa der Gegenwart. A Collection of Contemporary German Prose. Ed. Gudrun Isaak & Susan Ray KOSSUTH, KAREN C. & DAVID R. ANTAL. Alte Legenden und neue Literatur. NESTROY, ...

Tópico(s): Linguistic Education and Pedagogy

1986 - Wiley | Modern Language Journal

Artigo

David White,

... procedures (R. J. Read, G. D. Brayer, L. Jurasek & M. N. G. James, Biochemistry 23, 6570 (1984)). ...

Tópico(s): Computational Drug Discovery Methods

1986 - Royal Society | Philosophical Transactions of the Royal Society of London Series A Mathematical and Physical Sciences

Artigo Acesso aberto Revisado por pares

Reinhard Andress, St Louis, Lalande Ii, Thomas Stoyak, Daniel Wipf, Joseph Maintaining, Lakshmy Krishnan, Hwee Lee,

... Reinhard (St. Louis U., USA), James, Charles J., Jurasek, Barbara, Lalande II, John F., Lovik, Thomas A., Lund, Deborah, Stoyak, Daniel P., Tatlock, Lynne and Wipf, Joseph A. . Maintaining the momentum from high school to college: Report and recommendations. Die Unterrichtspraxis/Teaching German (Cherry Hill, NJ, USA), 35 , 1 (2002), 1—14. 03—231 Andrews, David R. (Georgetown U., USA.). Teaching the Russian heritage ...

Tópico(s): Second Language Learning and Teaching

2003 - Cambridge University Press | Language Teaching

Artigo Acesso aberto Revisado por pares

David G. Ryan, Tianwei Lin, Edward R. Brownie, William A. Bridger, William T. Wolodko,

... 954Crossref PubMed Scopus (36) Google Scholar, 3Wang T. Jurasek L. Bridger W.A. Biochemistry. 1972; 11: 2067- ...

Tópico(s): Plant biochemistry and biosynthesis

1997 - Elsevier BV | Journal of Biological Chemistry

Artigo Acesso aberto Revisado por pares

... epilepsy to proceed with surgery. 1 Laura L. Jurasek, 1 Daphne Quigley, 1 D. Barry Sinclair, 1 ...

Tópico(s): Pharmacological Effects and Toxicity Studies

2006 - Wiley | Epilepsia