Masako Kato, Tomoaki Tanase, Masahiro Mikuriya,
Reactions of CuX2.nH2O with the biscarboxylate ligand XDK (H2XDK = m-xylenediamine bis(Kemp's triacid imide)) ... series of dicopper(II) complexes, [Cu2(mu-OH)(XDK)(L)2]X (L = N,N,N',N'- ... phosphoric acid (HBNPP) to give [Cu2(mu-phosphate)(XDK)(L)2]NO3 (L = bpy, phosphate = DPP (11); ... bridged dicopper centers, yielding [Cu2(mu-Sugar-P)(XDK)(L)2] (Sugar-P = alpha-D-Glc-1- ... Mephen (b)) and [Cu2(mu-Gly-n-P)(XDK)(Mephen)2] (Gly-n-P = glycerol n-phosphate; ... fructose, respectively. The structure of [Cu2(mu-MNPP)(XDK)(phen)2(CH3OH)] (20) was characterized as a ...
Tópico(s): Metal-Catalyzed Oxygenation Mechanisms
2006 - American Chemical Society | Inorganic Chemistry
Daniel D. LeCloux, Stephen J. Lippard,
... with thallium ethoxide provided dithallium salts Tl2L (L = XDK, 7; PXDK, 8; and BXDK, 9). Reaction of ... MeCN afforded dinuclear acetonitrile adducts [Cu2L(MeCN)] (L = XDK, 10; PXDK, 11; and BXDK, 12) in high ... multigram quantities. The coordination chemistry of the Cu2(XDK) platform was explored with a range of ancillary ... the specified neutral donor ligand provided complexes [Cu2(XDK)(PPh3)2] (13), [Cu2(XDK)(2,6-Me2C6H3NC)3] (14a), [Cu2(XDK)(μ-2,6-Me2C6H3NC)(2,6-Me2C6H3NC)2] (14b), [Cu2(XDK)(NB)2] (15), [Cu2(XDK)(tmeda)] (17), [Cu2( ...
Tópico(s): Lanthanide and Transition Metal Complexes
1997 - American Chemical Society | Inorganic Chemistry
Tomoaki Tanase, Joanne W. Yun, Stephen J. Lippard,
... complexes were prepared by using the dinucleating ligand XDK [H2XDK = m-xylylenediamine bis(Kemp's triacid imide)]. Mononuclear [Zn(XDK)(H2O)] (1) reacts with 1 equiv of M( ... 4-pentanedionate) to afford the heterodimetallic compounds [ZnIIMII(XDK)(acac)2(CH3OH)2]·H2O (2·H2O, M = ... each contain a ZnIIMII dinuclear core bridged by XDK and acac ligands. The zinc and M atoms ... hydrogen phosphate afforded the bis(phosphate) complex [ZnCo(XDK){μ-η2-(PhO)2PO2}{η1-(PhO)2PO2}(CH3OH) ... yield). The ZnCo center is bridged by the XDK through its two carboxylate groups and by a ...
Tópico(s): Metal-Organic Frameworks: Synthesis and Applications
1996 - American Chemical Society | Inorganic Chemistry
Dietrich Steinhuebel, Peter Fuhrmann, Stephen J. Lippard,
A series of zirconium(IV) complexes, [ZrX2(XDK)], where XDK is the constrained carboxylate ligand m-xylylenediamine bis(Kemp's triacid imide), were prepared and structurally characterized. The solid state structure ... the mononuclear carboxylate alkyl complex [Zr(CH2Ph)2(XDK)] reveals that one benzyl group is bonded in ... metal center. The reactivity of [Zr(CH2Ph)2(XDK)] displays its electrophilic character toward nucleophiles strong enough ... the monoadduct [Zr(CH2Ph)2(4-tert-butylpyridine)(XDK)] and [Zr{η2-2,6-Me2PhNCCH2Ph}2(XDK)], ...
Tópico(s): Coordination Chemistry and Organometallics
1998 - Elsevier BV | Inorganica Chimica Acta
Tomoaki Tanase, Hiromi Inukai, Tomoko Onaka, Masako Kato, Shigenobu Yano, Stephen J. Lippard,
... analysis. Reactions of 11 (M = Zn) with [Zn(XDK)(H2O)] (21) or [Cu(XDK)(py)2] (22) (H2XDK = m-xylylenediamine bis(Kemp' ... formulated as [Zn2M'{(d-Glc)2-tacn}2(XDK)]Cl2 (M' = Zn (31), Cu (32)). The similar ... 22 afforded [Cu2M'{(d-Glc)2-tacn}2(XDK)]Cl2 (M' = Cu (33), Zn (34)). An X- ... trimetallic centers bridged by two carboxylate groups of XDK and two d-glucopyranosyl residues. The M···M' ... the carbohydrates, and a carboxylate oxygen atom of XDK ligand. The central metal ions sit in a ... tacn ligands and two carboxylate oxygen atoms of XDK. The deprotonated β-d-glucopyranosyl unit at the ...
Tópico(s): Carbohydrate Chemistry and Synthesis
2001 - American Chemical Society | Inorganic Chemistry
The dinuclear complex [Co2(μ-OH)(μ-XDK)(bpy)2(EtOH)](NO3), where XDK is the dinucleating dicarboxylate ligand m-xylylenediamine bis(Kemp's triacid imide) and bpy = 2,2'-bipyridine, ... of related dinuclear cobalt(II) complexes [Co2(μ-XDK)(NO3)2(CH3OH)2(H2O)], [Co2(μ-Cl)(μ-XDK)(bpy)2(EtOH)2](NO3), and [Co2(μ-XDK)(py)3(NO3)2] are described. Mononuclear complexes [Co(XDK)(bpy)(H2O)] and [Zn(XDK)(bpy)(H2O)] were also prepared and characterized. The ...
Tópico(s): Nitric Oxide and Endothelin Effects
1998 - American Chemical Society | Journal of the American Chemical Society
Tadashi Mizoguchi, Stephen J. Lippard,
... carboxylato)diiron(III) complexes [Fe(2)O(&mgr;-XDK)(bpy)(2)(NCS)(2)] (1), [Fe(2)O(&mgr;-XDK)(bpy)(2)((15)NCS)(2)] (1a), [Fe(2)O(&mgr;-XDK)(bpy)(2)(NCSe)(2)] (2), [Fe(2)O(&mgr;-XDK)(bpy)(2)(N(3))(2)] (3), and [Fe(2)O(&mgr;-XDK)(bpy)(2)((15)NNN)(2)] (3a), where XDK is the doubly deprotonated form of m-xylylenediamine ... oxo group and the two carboxylate groups of XDK. In the X-ray crystal structures of 1 ...
Tópico(s): Metal complexes synthesis and properties
1997 - American Chemical Society | Inorganic Chemistry
Daniel D. LeCloux, Roman Davydov, Stephen J. Lippard,
... Zn) analogues. Treatment of previously reported [Cu(2)(XDK)(MeCN)] (1) or [Cu(2)(PXDK)(MeCN)] (2), where H(2)XDK = m-xylylenediamine bis(Kemp's triacid imide) and ... 2)PXDK = the propyl derivative of H(2)XDK, with 1 equiv of silver(I) triflate, trifluoroacetate, ... X)(THF)(2)], where X = triflate and L = XDK (4), PXDK (5); X = trifluoroacetate and L = XDK (6) and [Cu(2)L(THF)(4)]X, where X = tetrafluoroborate, L = XDK (7), PXDK (8). Compound 8 was also prepared ...
Tópico(s): Magnetism in coordination complexes
1998 - American Chemical Society | Inorganic Chemistry
Joanne W. Yun, Tomoaki Tanase, Stephen J. Lippard,
... synthesized and characterized by employing the dinucleating ligand XDK, where H2XDK is m-xylylenediamine bis(Kemp's ... 2 equiv of sodium diphenyl phosphate with [Mg2(XDK)(CH3OH)4(H2O)2(NO3)](NO3), 1(NO3), afforded [Mg2(XDK){μ-η2-(PhO)2PO2}(CH3OH)3(H2O)(NO3)]·3CH3OH (2·3CH3OH) and [Mg2(XDK){μ-η2-(PhO)2PO2}{η1-(PhO)2PO2}(CH3OH) ... to that of structurally analogous dizinc(II), [Zn2(XDK){μ-η2-(PhO)2PO2}{η1-(PhO)2PO2}(CH3OH)2(H2O)] (5), and dicalcium(II), [Ca2(XDK){μ-η2-(PhO)2PO2}{η1-(PhO)2PO2}(CH3OH) ...
Tópico(s): Chemical Synthesis and Characterization
1996 - American Chemical Society | Inorganic Chemistry
Stephen P. Watton, Mindy I. Davis, Laura E. Pence, Julius Rebek, Stephen J. Lippard,
... dicarboxylate ligand xylenediamine bis-(Kemp's triacid imide) (XDK) and neocuproine (neo, 2,9-dimethyl-1,10- ... The X-ray structure of this complex, [Co(XDK)(neo)]·3CH3OH (1·dCH3OH) (monoclinic P2 1 /c, ... environment, with asymmetrical binding by the carboxylates of XDK. Complex 1 reacts readily with alkali metal salts to afford heterodimetallic complexes, such as [KCo(XDK)(neo)(PF6)] (2) and [Rb2Co2(XDK)2-(neo)2(H2O)(BPh4)2] (3). The ... of 2·2CH3CN and 3·2CHCl3 reveal that XDK undergoes a carboxylate shift upon formation of the ...
Tópico(s): Metal-Catalyzed Oxygenation Mechanisms
1995 - Elsevier BV | Inorganica Chimica Acta
Tadashi Mizoguchi, Roman Davydov, Stephen J. Lippard,
... carboxylato)diiron(III) complex [Fe2(μ-O)(μ-XDK)(CH3OH)6]2+, where XDK2- = the dianion of ... green bis(aqua) complex [Fe2(μ-O)(μ-XDK)(hfac)2(H2O)2] (3) was crystallographically characterized ... which is assigned as the (μ-hydroxo)(μ-XDK)bis(hfac)diiron(III) complex. Analytically pure samples of this [Fe2(μ-OH)(μ-XDK)(hfac)2(H2O)2]+ (4) cation were obtained ...
Tópico(s): Magnetism in coordination complexes
1999 - American Chemical Society | Inorganic Chemistry
Mireia Garcia‐Viloca, Ricard Gelabert, Àngels González‐Lafont, Miquel Moreno, José M. Lluch,
... hydrogen bond in a realistic model of hexabenzyloxymethyl-XDK [m-xylidenediamine-bis(Kemp's triacid)-imide] monoanion ... wave functions. Our results indicate that for hexabenzyloxymethyl-XDK monoanion, the first vibrational level appears above the ... region so that, as observed experimentally, the hexabenzyloxymethyl-XDK monoanion has a low-barrier hydrogen bond. Conversely, ... each case. We have found that for hexabenzyloxymethyl-XDK monoanion the chemical shift decreases as the temperatures ...
Tópico(s): Spectroscopy and Quantum Chemical Studies
1998 - American Chemical Society | Journal of the American Chemical Society
Susanna Herold, Stephen J. Lippard,
... the two pentanuclear complexes [Fe5(μ3-F)2(XDK)2(L)4(O2CPh)4], where L = pyridine ( ... 6](BF4)2, the deprotonated dinucleating dicarboxylate ligand XDK, H2XDK = m-xylylenediamine bis(Kemp's triacid)imide, ... or N-MeIm, afforded [Fe5(μ3-F)2(XDK)2(py)4(O2CPh)4] (1) and [Fe5(μ3-F)2(XDK)2(N-MeIm)4(O2CPh)4] (2), respectively. ...
Tópico(s): Metal complexes synthesis and properties
1997 - American Chemical Society | Inorganic Chemistry
Produção Nacional
Revisado por pares
Giuliano Queiroz Mostachio, Luciana Domingues de Oliveira, Aulus Cavalieri Carciofí, W. R. R. Vicente,
... the anesthetic effects of a xylazine-diazepam-ketamine (XDK) combination in roosters. Study design Prospective experimental trial. ... in two birds. Conclusions and clinical relevance The XDK combination was a useful anesthetic technique for typhlectomy ...
Tópico(s): Anesthesia and Sedative Agents
2008 - Elsevier BV | Veterinary Anaesthesia and Analgesia
Ralph Debusmann, Denys Duchier, Joachim Niehren,
... this paper, we present the XDG Development Kit (XDK), the first XDG-based grammar development system, which ... full use of its multi-paradigmatic nature. The XDK supports an expressive lexicon specification language which which ...
Tópico(s): Semantic Web and Ontologies
2005 - Springer Science+Business Media | Lecture notes in computer science
Susanna Herold, Stephen J. Lippard,
... to each iron(II) ion. In addition to XDK and PXDK, a variety of other ligands bridge ... carboxylate. The tris(carboxylate-bridged) complexes [Fe2(μ-XDK)(μ-O2CPh)(ImH)2(O2CPh)(MeOH)] (3) and [ ...
Tópico(s): Metalloenzymes and iron-sulfur proteins
1997 - American Chemical Society | Journal of the American Chemical Society
Tomoaki Tanase, Joanne W. Yun, Stephen J. Lippard,
... RETURN TO ISSUEPREVArticleNEXTMono- and Dinuclear Zinc Complexes of XDK, H2XDK = m-Xylenediamine Bis(Kemp's triacid imide), ...
Tópico(s): Organophosphorus compounds synthesis
1995 - American Chemical Society | Inorganic Chemistry
Produção Nacional
Revisado por pares
Selma de Jesus Bof Vêscovi, Cândida Çaniçali Primo, Hugo Cristo Sant’Anna, Maria Edla de Oliveira Bringuete, Roseane Vargas Rohr, Thiago Nascimento do Prado, Sheilla Diniz Silveira Bicudo,
... Engenharia de Software e utilizou o programa Intel XDK, para plataformas IOS e Android. O produto foi ...
Tópico(s): Health Education and Validation
2017 - UNIVERSIDADE FEDERAL DE SÃO PAULO | Acta Paulista de Enfermagem
Zhaoqing Wang, Harry H. Cheng,
... s XML developer's Kit for C/C++ (XDK), and Microsoft's XML parser. These toolkits reflect ...
Tópico(s): Parallel Computing and Optimization Techniques
2006 - IEEE Computer Society | IEEE Software
Stephen P. Watton, Peter Fuhrmann, Laura E. Pence, Stephen J. Lippard, Andréa Caneschi, Andrea Cornia, Gian Luca Abbati,
... bisher größte ringförmige Eisen(III)‐Verbindung. [{Fe(OH)(XDK)Fe 2 (OCH 3 ) 4 (O 2 CCH ...
Tópico(s): Lanthanide and Transition Metal Complexes
1997 - Wiley | Angewandte Chemie
Tomoaki Tanase, T. Aiko, Yasuhiro Yamamoto,
... 4] in methanol in the presence of Na2(xdk)[H2xdk =m-xylenediamine bis(Kemp's triacid imide)] ...
Tópico(s): Organometallic Complex Synthesis and Catalysis
1996 - Royal Society of Chemistry | Chemical Communications
Lisa C. Jeffrey, Jonathan Weitsman,
... assign to every two-manifold Cg the quantization XDk(Cg) of the system (Pg, CO, 9, V), ...
Tópico(s): Homotopy and Cohomology in Algebraic Topology
1993 - Elsevier BV | Topology
Produção Nacional
Revisado por pares
André Augusto Menegassi, André Takeshi Endo,
... sencha.com), IONIC (http://ionicframework.com/), and Intel XDK (https://software.intel.com/xdk). Unlike native apps, hybrid apps have the advantage ...
Tópico(s): Software Testing and Debugging Techniques
2019 - Institution of Engineering and Technology | IET Software
Produção Nacional
Revisado por pares
Jairo Francesco da Silva, Maria Adelina Raupp Sganzerla, Marlise Geller,
... para aplicações móveis, usando ferramentas como o Intel XDK para codificar programação Web e acessar recursos de ...
Tópico(s): Assistive Technology in Communication and Mobility
2021 - Associação Sul-Rio-Grandense de Pesquisadores em História da Educação (ASPHE) | RENOTE
... formula of the sum∑1≤n1,n2,…,nl≤xdk(n12+n22+⋯+nl2), where n1,n2,…,nl∈Z+, ...
Tópico(s): Advanced Mathematical Theories
2020 - Elsevier BV | Journal of Number Theory
... designing a database My SQL and application software XDK For smart devices. The results show that 75. ...
Tópico(s): IoT and GPS-based Vehicle Safety Systems
2020 - IOP Publishing | IOP Conference Series Materials Science and Engineering
Mikhail A. Vorotyntsev, A. E. Antipov,
... the diffusion (zd) and kinetic (zk) layer thicknesses, xdk = zd/zk. On the contrary, significant deviation of ... revealed for very large values of this parameter, xdk, (well above 10) and strong current passage. This ... for very large values of the principal parameter, xdk, and any value of the passing current.
Tópico(s): Electrocatalysts for Energy Conversion
2018 - Elsevier BV | Electrochimica Acta
... recombinants XDD (EG.5.1.1/JN.1), XDK (XBB*/JN.1.1.1). There is only ...
Tópico(s): SARS-CoV-2 and COVID-19 Research
2024 - European Society of Medicine | Medical Research Archives
Paola Pinheiro bernardi Primo, Angélica Espinosa Miranda, Hugo Cristo Sant ́anna,
... O sistema foi desenvolvido utilizando o programa Intel XDK, e teve como público-alvo inicial alunos de ...
Tópico(s): Mosquito-borne diseases and control
2017 - | Revista Guará
Produção Nacional
Jorge Henrique Jacinto Júnior, Karla Marques da Rocha, Rodrigo Machado, Willian Gerstberger, Gustavo Girardon, Pedro Garcia, Lukas Gaedicke,
... Bootstrap, AJAX, PHP, Mysql e as ferramentas Intel XDK, Balsamic Mockup e Bitbucket constituem as tecnologias. Oficinas ...
Tópico(s): Business and Management Studies
2016 - | Anais ... Workshops do Congresso Brasileiro de Informática na Educação