Silver/polysaccharide-based nanofibrous materials synthesized from green chemistry approach
2015; Elsevier BV; Volume: 136; Linguagem: Inglês
10.1016/j.carbpol.2015.09.014
ISSN1879-1344
AutoresMaría de los Ángeles Martínez-Rodríguez, Marco A. Garza-Navarro, Iván E. Moreno‐Cortez, Raúl Lucio Porto, Virgilio Ángel González González,
Tópico(s)Supercapacitor Materials and Fabrication
ResumoIn this contribution a novel green chemistry approach for the synthesis of nanofibrous materials based on blends of carboxymethyl-cellulose (CMC)–silver nanoparticles (AgNPs) composite and polyvinyl-alcohol (PVA) is proposed. These nanofibrous materials were obtained from the electrospinning of blends of aqueous solutions of CMC–AgNPs composite and PVA, which were prepared at different CMC/PVA weight ratios in order to electrospin nanofibers applying a constant tension of 15 kV. The synthesized materials were characterized by means of transmission electron microscopy, scanning electron microscopy; as well as Fourier-transform infrared, ultraviolet and Raman spectroscopic techniques. Experimental evidence suggests that the diameter of the nanofibers is thinner than any other reported in the literature regarding the electrospinning of CMC. This feature is related to the interactions of AgNPs with carboxyl functional groups of the CMC, which diminish those between the later and acetyl groups of PVA.
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