Kinetic Theory and Rheology of Macromolecular Solutions
1976; Wiley; Linguagem: Inglês
10.1002/9780470142547.ch2
ISSN1934-4791
AutoresC. F. Curtiss, R. Byron Bird, Ole Hassager,
Tópico(s)Polymer crystallization and properties
ResumoThis chapter contains sections titled: Introduction Definitions, Nomenclature, and Coordinates Euler Angles and Internal Coordinates The Time Evolution of the Dynamical Sate of the System Time-Evolution of Ensemble Averages and the Equations of Change Contracted Distribution Functions and Average Values General Expressions for the Fluxes in Terms of the Distribution Functions f α and f αβ Time-Evolution of the Singlet Distribution Function f α Kinetic Equations in Configuration Space Several Assumptions Approximate “Diffusion Equation” for ψα in Configuration Space An Expression for the Momentum-Flux Tensor in Terms of the Configuration-Space Distribution Function The Momentum-Flux Tensor Expressions of Kramers, Kirkwood, Kotaka, and Fixman Comments on the Symmetry of the Momentum-Flux Tensor An Alternate Form for the Momentum-Flux Tensor: A Generalization of the Giesekus Equation The Second-Order Fluid Constants for Arbitrary Bead-Spring-Rod Macromolecular Models The High-Frequency Dynamic Viscosity of Arbitrary Bead-Spring-Rod Macromolecular Models Conclusions
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