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Solvent Effects on Transition States and Reaction Rates

1974; Linguagem: Inglês

10.1002/9780470171905.ch1

1934-4821

Michael H. Abraham,

Free Radicals and Antioxidants

Solvent Effects on Transition States and Reaction Rates M. H. Abraham, M. H. Abraham Department of Chemistry, University of Surrey, Guildford, SurreySearch for more papers by this author M. H. Abraham, M. H. Abraham Department of Chemistry, University of Surrey, Guildford, SurreySearch for more papers by this author Book Editor(s):Andrew Streitwieser Jr., Andrew Streitwieser Jr. Department of Chemistry, University of California, Berkeley, CaliforniaSearch for more papers by this authorRobert W. Taft, Robert W. Taft Department of Chemistry, University of California, Irvine, CaliforniaSearch for more papers by this author First published: 01 January 1974 https://doi.org/10.1002/9780470171905.ch1Citations: 75Book Series:Progress in Physical Organic Chemistry AboutPDFPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShareShare a linkShare onEmailFacebookTwitterLinkedInRedditWechat Summary This chapter contains sections titled: Introduction Correlations of Reaction Rate with Solvent Parameters Solvent Effects on the Free Energies of Electrolytes, Nonelectrolytes, and Transition States Determinations of Solvent Effects on the Free Energies of Transition States Methods for the Estimation of Transition State Properties from Values of ΔGt°(Tr) References Menschutkin, N. A., Z. Phys. Chem., 6, 41 (1890). 10.1515/zpch-1890-0107 Google Scholar Moelwyn-Hughes, E. A., Kinetics of Reactions in Solution, Clarendon Press, Oxford, (a) 1st ed., 1933, Ch. 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