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Use of Methylene Chloride as a C1 Unit in N,N-Dialkylaminomethylation Reaction

1993; Taylor & Francis; Volume: 23; Issue: 6 Linguagem: Inglês

10.1080/00397919308009843

1532-2432

Florence Souquet, Thierry Martens, Maurice‐Bernard Fleury,

Ammonia Synthesis and Nitrogen Reduction

Abstract Mannich products have been isolated in good yields with methylene chloride as a C1 unit, instead of formaldehyde. It is evidenced that, contrary to previous understanding, a high pressure procedure is not necessary required and that the methylene bisamines function as intermediates.