High‐Performance LiNi 0.5 Mn 1.5 O 4 Spinel Controlled by Mn 3+ Concentration and Site Disorder
2012; Volume: 24; Issue: 16 Linguagem: Inglês
10.1002/adma.201104767
ISSN1521-4095
AutoresJie Xiao, Xilin Chen, Peter V. Sushko, Maria L. Sushko, Libor Kovařík, Jijun Feng, Zhiqun Deng, Jianming Zheng, Gordon L. Graff, Zimin Nie, Daiwon Choi, Jun Liu, Ji‐Guang Zhang, M. Stanley Whittingham,
Tópico(s)Ferroelectric and Piezoelectric Materials
ResumoAdvanced MaterialsVolume 24, Issue 16 p. 2109-2116 Communication High-Performance LiNi0.5Mn1.5O4 Spinel Controlled by Mn3+ Concentration and Site Disorder Jie Xiao, Corresponding Author Jie Xiao [email protected] Pacific Northwest National Laboratory, Richland, WA99352, USAPacific Northwest National Laboratory, Richland, WA99352, USA.===Search for more papers by this authorXilin Chen, Xilin Chen Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorPeter V. Sushko, Peter V. Sushko Department of Physics and Astronomy and London, Centre for Nanotechnology, University College London, Gower Street, London, WC1E 6BT, UKSearch for more papers by this authorMaria L. Sushko, Maria L. Sushko Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorLibor Kovarik, Libor Kovarik Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorJijun Feng, Jijun Feng Department of Chemistry, State University of New York at Binghamton (SUNY Binghamton), New York 13902, USASearch for more papers by this authorZhiqun Deng, Zhiqun Deng Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorJianming Zheng, Jianming Zheng Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorGordon L. Graff, Gordon L. Graff Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorZimin Nie, Zimin Nie Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorDaiwon Choi, Daiwon Choi Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorJun Liu, Jun Liu Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorJi-Guang Zhang, Corresponding Author Ji-Guang Zhang [email protected] Pacific Northwest National Laboratory, Richland, WA99352, USAPacific Northwest National Laboratory, Richland, WA99352, USA.===Search for more papers by this authorM. Stanley Whittingham, M. Stanley Whittingham Department of Chemistry, State University of New York at Binghamton (SUNY Binghamton), New York 13902, USASearch for more papers by this author Jie Xiao, Corresponding Author Jie Xiao [email protected] Pacific Northwest National Laboratory, Richland, WA99352, USAPacific Northwest National Laboratory, Richland, WA99352, USA.===Search for more papers by this authorXilin Chen, Xilin Chen Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorPeter V. Sushko, Peter V. Sushko Department of Physics and Astronomy and London, Centre for Nanotechnology, University College London, Gower Street, London, WC1E 6BT, UKSearch for more papers by this authorMaria L. Sushko, Maria L. Sushko Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorLibor Kovarik, Libor Kovarik Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorJijun Feng, Jijun Feng Department of Chemistry, State University of New York at Binghamton (SUNY Binghamton), New York 13902, USASearch for more papers by this authorZhiqun Deng, Zhiqun Deng Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorJianming Zheng, Jianming Zheng Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorGordon L. Graff, Gordon L. Graff Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorZimin Nie, Zimin Nie Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorDaiwon Choi, Daiwon Choi Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorJun Liu, Jun Liu Pacific Northwest National Laboratory, Richland, WA99352, USASearch for more papers by this authorJi-Guang Zhang, Corresponding Author Ji-Guang Zhang [email protected] Pacific Northwest National Laboratory, Richland, WA99352, USAPacific Northwest National Laboratory, Richland, WA99352, USA.===Search for more papers by this authorM. Stanley Whittingham, M. Stanley Whittingham Department of Chemistry, State University of New York at Binghamton (SUNY Binghamton), New York 13902, USASearch for more papers by this author First published: 19 March 2012 https://doi.org/10.1002/adma.201104767Citations: 413Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract The complex correlation between Mn3+ ions and the disordered phase in the lattice structure of high voltage spinel, and its effect on the charge transport properties, are revealed through a combination of experimental study and computer simulations. Superior cycling stability is achieved in LiNi0.45Cr0.05Mn1.5O4 with carefully controlled Mn3+ concentration. At 250th cycle, capacity retention is 99.6% along with excellent rate capabilities. Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description adma_201104767_sm_suppl.pdf286.2 KB suppl Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. 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