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The Apparent Constant-Phase-Element Behavior of an Ideally Polarized Blocking Electrode

2007; Institute of Physics; Volume: 154; Issue: 2 Linguagem: Inglês

10.1149/1.2398882

1945-7111

Vicky Mei-Wen Huang, Vincent Vivier, Mark E. Orazem, Nadine Pébère, Bernard Tribollet,

Smart Materials for Construction

Two numerical methods were used to calculate the influence of geometry-induced current and potential distributions on the impedance response of an ideally polarized disk electrode. A coherent notation is proposed for local and global impedance which accounts for global, local, local interfacial, and both global and local ohmic impedances. The local and ohmic impedances are shown to provide insight into the frequency dispersion associated with the geometry of disk electrodes. The high-frequency global impedance response has the appearance of a constant-phase element (CPE) but can be considered to be only an apparent CPE because the CPE exponent α is a function of frequency.