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Photoelectron Spectra and Electronic Structure of Some Steroids

1985; De Gruyter; Volume: 40; Issue: 7 Linguagem: Inglês

10.1515/zna-1985-0709

1865-7109

Norman S. Bhacca, L. Klasinc̆,

Chemistry and Stereochemistry Studies

Gas phase Hel photoelectron spectra of 5ɑ-androstane, 5ɑ-androstan-3-one and 5ɑ-androstan- 17-one compared with those of other saturated cyclic hydrocarbons and ketones indicated that the electronic effect of a keto group in steroids is rather local i.e. extending over about two rings.