Portal de Periódicos da CAPES

Legume saponins of Gleditsia japonica Miquel. IV. 13C-Nuclear magnetic resonance spectral studies for structure elucidation of gleditsia saponins B and C.

1982; Pharmaceutical Society of Japan; Volume: 30; Issue: 8 Linguagem: Inglês

10.1248/cpb.30.2747

1347-5223

Takao Konoshima, TOKUNOSUKE SAWADA,

Plant biochemistry and biosynthesis

Two triterpenoid saponins, gleditsia saponins B (GS-B, XIX) and C (GS-C, XX) which were isolated from Gleditsia japonica cv. 'Saponifera', were characterized as 3, 28-O-bisglycosides of echinocystic acid acylated with monoterpene carboxylic acids. On the basis of 13C-nuclear magnetic resonance spectra and the results of chemical and enzymatic hydrolysis, it was established that the positions of acylation with the mono-terpenes (IV) and (V) were C-2 and C-3, respectively, of the terminal rhamnose of the 28-O-glycoside moiety in the molecules of GS-C and GS-B.