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Equilibrium Constant for Boron Isotope Exchange between BF3 and BF3·O (CH3)2

1962; American Institute of Physics; Volume: 37; Issue: 3 Linguagem: Inglês

10.1063/1.1701372

1520-9032

A. A. Palko, G. M. Bègun, L. Landau,

Boron Compounds in Chemistry

The isotopic equilibrium constant for boron exchange between BF3 and BF3·O (CH3)2 has been measured at −8°, 4°, and 22°C. The measured values are compared with values calculated from infrared and Raman spectral data. The physical basis for boron isotope fractionation in systems of this type is discussed.