Oxidation of formate on hydrogen-loaded palladium
2002; Elsevier BV; Volume: 27; Issue: 1 Linguagem: Inglês
10.1016/s0360-3199(01)00086-6
ISSN1879-3487
Autores Tópico(s)Electronic and Structural Properties of Oxides
ResumoHydrogen occluded in palladium assists in the electrooxidation of formate ions at its surface, by chemically reacting with strongly adsorbed poisoning species and contributing to their release from the surface. Reaction between emerging occluded hydrogen and adsorbed CO regenerates surface sites for the continuous electrochemical oxidation of formate ions.
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