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Nanocomposite anodes for lithium-ion batteries based on Sno 2 on multiwalled carbon nanotubes

2013; Wiley; Volume: 38; Issue: 4 Linguagem: Inglês

10.1002/er.3143

1099-114X

Mehmet Oğuz Güler, O. Cevher, Tuğrul Çetіnkaya, U. Tocoglu, Hatem Akbulut,

Supercapacitor Materials and Fabrication

International Journal of Energy ResearchVolume 38, Issue 4 p. 487-498 Special Issue on Nano Energy Technologies Nanocomposite anodes for lithium-ion batteries based on Sno2 on multiwalled carbon nanotubes Mehmet Oguz Guler, Mehmet Oguz Guler Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, TurkeySearch for more papers by this authorOzgur Cevher, Ozgur Cevher Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, TurkeySearch for more papers by this authorTugrul Cetinkaya, Tugrul Cetinkaya Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, TurkeySearch for more papers by this authorUbeyd Tocoglu, Ubeyd Tocoglu Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, TurkeySearch for more papers by this authorHatem Akbulut, Corresponding Author Hatem Akbulut Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, Turkey Correspondence: Hatem Akbulut, Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187, Sakarya, Turkey. E-mail: [email protected]Search for more papers by this author Mehmet Oguz Guler, Mehmet Oguz Guler Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, TurkeySearch for more papers by this authorOzgur Cevher, Ozgur Cevher Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, TurkeySearch for more papers by this authorTugrul Cetinkaya, Tugrul Cetinkaya Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, TurkeySearch for more papers by this authorUbeyd Tocoglu, Ubeyd Tocoglu Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, TurkeySearch for more papers by this authorHatem Akbulut, Corresponding Author Hatem Akbulut Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187 Sakarya, Turkey Correspondence: Hatem Akbulut, Engineering Faculty, Metallurgical and Materials Engineering Department, Sakarya University, Esentepe Campus, 54187, Sakarya, Turkey. E-mail: [email protected]Search for more papers by this author First published: 19 December 2013 https://doi.org/10.1002/er.3143Citations: 35Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat SUMMARY In this study, multiwall carbon nanotube (MWCNT) based buckypapers were produced via vacuum filtration techniques. The surfaces of the buckypapers were then coated with tin oxide (SnO2) thin films via radio frequency magnetron sputtering techniques. In order to evaluate the electrochemical performance of SnO2 coated buckypapers, bare SnO2 thin films were also deposited onto stainless steel substrates. Bare SnO2 was deposited on the stainless steel coin and on the functionalized MWCNT buckypapers. The SnO2/MWCNT nanocomposites have shown to exhibit desirable electrochemical performances as the negative electrodes for the lithium-ion batteries. MWCNTs not only suppressed the mechanical degradation of SnO2 and, therefore, provided the composite electrode with excellent capacity retention (>700 mAhg−1 after 100 cycles) but also enhanced the electronic conductivity of the electrodes leading to excellent rate capability. The gradient composition of SnO2 from the surface to the center of the buckypaper in the SnO2/MWCNT nanocomposites has been shown to be critical for mitigating the mechanical degradation of electrodes. A nanocomposite produced at 5% O2 + 95 Ar atmosphere gave the best performance, exhibiting significantly high reversible capacity and excellent cycling ability. The excellent lithium storage and rate capacity performance of gradient composition SnO2/MWCNT core-shell nanocomposites make them promising anode materials for lithium-ion batteries. Copyright © 2013 John Wiley & Sons, Ltd. REFERENCES 1 Todd ADW, Ferguson PP, Fleischauerand MD, Dahn JR. Tin-based materials as negative electrodes for Li-ion batteries: combinatorial approaches and mechanical methods. International Journal of Energy Research 2010; 34: 535–555. 2 Zhao B, Zhang G, Song J, Jiang Y, Zhuang H, Liu P, Fang T. Bivalent tin ion assisted reduction for preparing graphene /SnO2 composite with good cyclic performance and lithium storage capacity. Electrochimica Acta 2011; 56: 7340–7346. 3 Ahn D, Xiao X, Li Y, Sachdev AK, Park HW, Yu A, Chen Z. 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