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Artigo Revisado por pares
BIBTEX RIS

Pd‐Catalyzed Tandem Chemoselective Synthesis of 2‐Arylbenzofurans using Threefold Arylating Triarylbismuth Reagents

2012; Wiley; Volume: 2013; Issue: 4 Linguagem: Inglês

10.1002/ejoc.201201314

ISSN

1434-193X

Autores

Maddali L. N. Rao, Deepak N. Jadhav, Priyabrata Dasgupta,

Tópico(s)

Catalytic Alkyne Reactions

Resumo

Abstract A tandem chemoselective synthesis of 2‐arylbenzofurans was accomplished from o ‐hydroxy‐ gem ‐(dibromovinyl)benzenes and BiAr 3 reagents under palladium‐catalyzed conditions. This unique and synthetically valuable strategy proceeds through three consecutive coupling reactions involving triarylbismuth reagents and provides 2‐arylbenzofuran products in high yields.

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