The Reaction of Methyl Radicals with Aceto- and Propio-Nitrile
1954; American Institute of Physics; Volume: 22; Issue: 6 Linguagem: Inglês
10.1063/1.1740267
ISSN1520-9032
Autores Tópico(s)Photochemistry and Electron Transfer Studies
ResumoThe reaction of CD3 radicals with aceto- and propio-nitrile has been studied over the temperature range 100 to 300°C at various intensities. The CD3 radicals were produced by photodecomposition of acetone-d6. As activation energies for the reactions CD3+CH3CN→CD3H+CH2CNand CD3+C2H5CN→CD3H+C2H4CN,we obtained E2=10±0.5 kcal and E3=8.5±0.5 kcal.
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