Chain transfer reactions in the polymerization of vinyl chloride
1961; Wiley; Volume: 53; Issue: 158 Linguagem: Inglês
10.1002/pol.12005315824
ISSN1542-6238
Autores Tópico(s)Advanced Polymer Synthesis and Characterization
ResumoAbstract The participation of chain transfer reactions in the polymerization of vinyl chloride in solutions has been elucidated. Isopropyl chloride, 2,4‐dichloropentane, and 2,4,6‐trichloroheptane were used as solvents. The transfer constants for the solvents were determined ( C a at 50°C. for dimer and trimer equals to 5 × 10 −4 ), which allows estimation of the value of chain transfer with polyvinyl chloride molecules in solution.
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