Nd 2 K 2 IrO 7 und Sm 2 K 2 IrO 7 : Normaldrucksynthese komplexer Iridium(VI)‐oxide
2008; Wiley; Volume: 121; Issue: 1 Linguagem: Estoniano
10.1002/ange.200804045
ISSN1521-3757
AutoresSamuel J. Mugavero, Mark D. Smith, Won‐Sub Yoon, Hans‐Conrad zur Loye,
Tópico(s)Magnetic and transport properties of perovskites and related materials
ResumoAngewandte ChemieVolume 121, Issue 1 p. 221-224 Zuschrift Nd2K2IrO7 und Sm2K2IrO7: Normaldrucksynthese komplexer Iridium(VI)-oxide† Correction(s) for this article Nd2K2IrO7 und Sm2K2IrO7: Normaldrucksynthese komplexer Iridium(VI)-oxide Samuel J. Mugavero Dr., Mark D. Smith Dr., Won-Sub Yoon Dr., Hans-Conrad zur Loye Prof. Dr., Volume 121Issue 6Angewandte Chemie pages: 1023-1023 First Published online: January 27, 2009 Samuel J. Mugavero III Dr., Samuel J. Mugavero III Dr. Department of Chemisrty and Biochemistry, University of South Carolina, Columbia, SC 29208 (USA), Fax: (+1) 803-777-8508Search for more papers by this authorMark D. Smith Dr., Mark D. Smith Dr. Department of Chemisrty and Biochemistry, University of South Carolina, Columbia, SC 29208 (USA), Fax: (+1) 803-777-8508Search for more papers by this authorWon-Sub Yoon Dr., Won-Sub Yoon Dr. Chemistry Department, Brookhaven National Laboratory, Upton, NY 11973 (USA)Search for more papers by this authorHans-Conrad zur Loye Prof. Dr., Hans-Conrad zur Loye Prof. Dr. [email protected] Department of Chemisrty and Biochemistry, University of South Carolina, Columbia, SC 29208 (USA), Fax: (+1) 803-777-8508Search for more papers by this author Samuel J. Mugavero III Dr., Samuel J. Mugavero III Dr. Department of Chemisrty and Biochemistry, University of South Carolina, Columbia, SC 29208 (USA), Fax: (+1) 803-777-8508Search for more papers by this authorMark D. Smith Dr., Mark D. Smith Dr. Department of Chemisrty and Biochemistry, University of South Carolina, Columbia, SC 29208 (USA), Fax: (+1) 803-777-8508Search for more papers by this authorWon-Sub Yoon Dr., Won-Sub Yoon Dr. Chemistry Department, Brookhaven National Laboratory, Upton, NY 11973 (USA)Search for more papers by this authorHans-Conrad zur Loye Prof. Dr., Hans-Conrad zur Loye Prof. Dr. [email protected] Department of Chemisrty and Biochemistry, University of South Carolina, Columbia, SC 29208 (USA), Fax: (+1) 803-777-8508Search for more papers by this author First published: 19 December 2008 https://doi.org/10.1002/ange.200804045Citations: 5 † Diese Arbeit wurde gefördert durch die National Science Foundation, Grant DMR:0450103 und DMR:0804209. Read the full textAboutPDF ToolsRequest permissionAdd to favorites ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Graphical Abstract Höchstoxidierte Iridiumoxide mit Iridium ausschließlich in der Oxidationsstufe +VI wurden durch Normaldrucksynthese in einer Hydroxidschmelze erhalten und röntgenkristallographisch untersucht. Das Bild zeigt die Struktur und deren Zerlegung in einzelne Bausteine: IrO6-Oktaeder (schwarz) mit den Schichten der KO10-Polyeder (braun) und schichtartige Einheiten der Nd/SmO10-Polyeder (blau). Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description ange_200804045_sm_miscellaneous_information.pdf97.9 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. References 1G. Demazeau, B. Buffat, F. Menil, L. Fournes, M. Pouchard, J. M. Dance, P. Fabritchnyi, P. Hagenmuller, Mater. Res. Bull. 1981, 16, 1465. 10.1016/0025-5408(81)90067-2 CASWeb of Science®Google Scholar 2G. Demazeau, B. Buffat, M. Pouchard, P. Hagenmuller, J. Solid State Chem. 1982, 45, 88. 10.1016/0022-4596(82)90294-8 CASWeb of Science®Google Scholar 3G. Demazeau, D.-Y. Jung, Eur. J. Solid State Inorg. 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Sie schienen etwas feuchtigkeitsempfindlich zu sein (wahrscheinlich wegen der ungewöhnlich hohen Oxidationsstufe des Iridiums) und wurden deshalb im Vakuumexsikkator aufbewahrt. Google Scholar 53Kristallographische Daten für Nd2K2IrO7: Z=6, M=670.88 g mol−1, Kristallabmessungen 0.06×0.03×0.02 mm3, hexagonale Morphologie, Raumgruppe Rc, a=5.73260(10), c=38.0887(15) Å, V=1084.00(5) Å3, ρber.=6.166 g cm−3, F(000)=1746, λ=0.71073 Å, T=294 K, μ=33.668 mm−1; Flächendetektor Bruker SMART Apex CCD; 6869 Reflexe, davon 545 symmetrieunabhängig, Rint=0.0485; Strukturlösung mit Direkten Methoden, Verfeinerung gegen F2 (2θmax=70.2°), Multiscan-Absorptionskorrektur, R1(I>2σ(I))=0.0229, wR2=0.0448, GoF=1.054. 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Zur Monochromatisierung der Strahlung wurde ein Paar von Si(111)-Kristallen verwendet. Frequenzverunreinigungen wurden durch Verstellen des Monochromators unterdrückt, indem die Intensität der einfallenden Röntgenstrahlung um ca. 10 % vermindert wurde. Um Probleme mit verschobenen Energiewerten zu vermeiden, wurden die Referenzspektren bei jeder Messung unter Gebrauch einer Ir-Metallfolie gleichzeitig aufgenommen. Google Scholar 57H.-H. Choy, D.-K. Kim, S.-H. Hwang, G. Demazeau, D.-Y. Jung, J. Am. Chem. Soc. 1995, 117, 8857. 10.1021/ja00139a022 Web of Science®Google Scholar Citing Literature Volume121, Issue1December 22, 2008Pages 221-224 This is the German version of Angewandte Chemie. Note for articles published since 1962: Do not cite this version alone. Take me to the International Edition version with citable page numbers, DOI, and citation export. We apologize for the inconvenience. ReferencesRelatedInformation
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