Sensitised near-infrared emission from lanthanides using a covalently-attached Pt(ii) fragment as an antenna groupElectronic supplementary information (ESI) available: characterisation data and luminescence spectra. See http://www.rsc.org/suppdata/cc/b3/b301878d/
2003; Royal Society of Chemistry; Issue: 10 Linguagem: Inglês
10.1039/b301878d
ISSN1364-548X
AutoresN.M. Shavaleev, L.P. Moorcraft, Simon J. A. Pope, Zöe R. Bell, Stephen Faulkner, Michael D. Ward,
Tópico(s)Organometallic Complex Synthesis and Catalysis
ResumoIn a series of heterodinuclear complexes in which a Pt(PPh3)2(catecholate) chromophore is covalently linked to a lanthanide tris(diketonate) unit, sensitised near-IR emission from Yb(III), Nd(III) and Er(III) occurs on excitation of the Pt(II) chromophore at 520 nm.
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