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BIBTEX RIS

Direct accessibility of mixed-metal ( iii / ii ) acid sites through the rational synthesis of porous metal carboxylates

2015; Royal Society of Chemistry; Volume: 51; Issue: 50 Linguagem: Inglês

10.1039/c5cc02550h

ISSN

1364-548X

Autores

Suwimol Wongsakulphasatch, Farid Nouar, Julien Rodriguez, L Anderson Scott, Clément Le Guillouzer, Thomas Devic, Patricia Horcajada, Jean‐Marc Grenèche, Philip L. Llewellyn, Alexandré Vimont, Guillaume Clet, Marco Daturi, Christian Serre,

Tópico(s)

Advanced Photocatalysis Techniques

Resumo

The scalable and environmentally-friendly synthesis of mixed Fe(III)/M(II) (M = Ni, Co, Mg) polycarboxylate porous MOFs based on the Secondary Building Unit approach is reported. A combination of in situ infrared spectroscopy, (57)Fe Mössbauer spectrometry and adsorption microcalorimetry confirms the direct accessibility of the iron(III) and metal(II) sites under low temperature activation conditions.

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