X-ray fluorescence determination of the manganese valence state and speciation in manganese ores
2015; Wiley; Volume: 44; Issue: 6 Linguagem: Inglês
10.1002/xrs.2619
ISSN1097-4539
AutoresВ. М. Чубаров, D. S. Suvorova, А. В. Мухетдинова, А. L. Finkelshtein,
Tópico(s)X-ray Diffraction in Crystallography
ResumoX-Ray SpectrometryVolume 44, Issue 6 p. 436-441 Research article X-ray fluorescence determination of the manganese valence state and speciation in manganese ores Victor Chubarov, Corresponding Author Victor Chubarov Vinogradov Institute of Geochemistry, SB RAS, 1A Favorsky Str., 664033 Irkutsk, Russia Correspondence to: Victor Chubarov, Institute of Geochemistry, SB RAS, 1A Favorsky Str., 664033, Irkutsk, Russia. E-mail: [email protected]Search for more papers by this authorDarya Suvorova, Darya Suvorova Institute of the Earth's crust, SB RAS, 128 Lermontov Str., 664033 Irkutsk, RussiaSearch for more papers by this authorAnastasya Mukhetdinova, Anastasya Mukhetdinova Vinogradov Institute of Geochemistry, SB RAS, 1A Favorsky Str., 664033 Irkutsk, RussiaSearch for more papers by this authorAlexander Finkelshtein, Alexander Finkelshtein Vinogradov Institute of Geochemistry, SB RAS, 1A Favorsky Str., 664033 Irkutsk, RussiaSearch for more papers by this author Victor Chubarov, Corresponding Author Victor Chubarov Vinogradov Institute of Geochemistry, SB RAS, 1A Favorsky Str., 664033 Irkutsk, Russia Correspondence to: Victor Chubarov, Institute of Geochemistry, SB RAS, 1A Favorsky Str., 664033, Irkutsk, Russia. E-mail: [email protected]Search for more papers by this authorDarya Suvorova, Darya Suvorova Institute of the Earth's crust, SB RAS, 128 Lermontov Str., 664033 Irkutsk, RussiaSearch for more papers by this authorAnastasya Mukhetdinova, Anastasya Mukhetdinova Vinogradov Institute of Geochemistry, SB RAS, 1A Favorsky Str., 664033 Irkutsk, RussiaSearch for more papers by this authorAlexander Finkelshtein, Alexander Finkelshtein Vinogradov Institute of Geochemistry, SB RAS, 1A Favorsky Str., 664033 Irkutsk, RussiaSearch for more papers by this author First published: 07 April 2015 https://doi.org/10.1002/xrs.2619Citations: 6Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onEmailFacebookTwitterLinkedInRedditWechat Abstract This work concerns determination of the manganese valence state and speciation by wavelength-dispersive X-ray fluorescence analysis. The authors investigated the effect of the manganese valence state and speciation on the intensity of some К-series lines of the X-ray emission spectrum for the samples of manganese compounds. The intensities of MnKβ5 line and MnKβ′ satellite are least influenced by speciation, and they may be used for evaluating the manganese valence state for the samples containing low iron. The intensities of MnKβ″ and MnKβx satellites may be employed for assessing the manganese speciation. The results of X-ray fluorescence determination of the manganese valence state and speciation in the manganese ores of the South Ural deposits agree with the X-ray diffraction data. 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