B-α-[AsW 9 O 33 ] 9− polyoxometalates incorporating hexanuclear uranium {U 6 O 8 }-like clusters bearing the U IV form or unprecedented mixed valence U IV /U VI involving direct U VI O

Artigo Revisado por pares

B-α-[AsW 9 O 33 ] 9− polyoxometalates incorporating hexanuclear uranium {U 6 O 8 }-like clusters bearing the U IV form or unprecedented mixed valence U IV /U VI involving direct U VI O–U IV bonding

2015; Royal Society of Chemistry; Volume: 44; Issue: 46 Linguagem: Inglês

10.1039/c5dt02932e

ISSN

1477-9234

Autores

Sylvain Duval, S. Sobanska, Pascal Roussel, Thierry Loiseau,

Tópico(s)

Radioactive element chemistry and processing

Resumo

Nanosized uranium clusters involving a rare U VI O–U IV bonding linkage are stabilized by the B-α-[AsW 9 O 33 ] polyanionic unit.

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