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BIBTEX RIS

A three-dimensional zeolite-like organic–inorganic hybrid material constructed from {CuMo2O8N}n double helical chains linked via [Cu(4,4′-bpy)]n fragmentsElectronic supplementary information (ESI) available: Fig. S1:χMT vs. T and χM vs. T plots for compound 1. See http://www.rsc.org/suppdata/cc/b1/b108704e/

2001; Royal Society of Chemistry; Issue: 2 Linguagem: Inglês

10.1039/b108704e

ISSN

1364-548X

Autores

Can‐Zhong Lu, Chuan‐De Wu, Shao‐Fang Lu, Jia‐Cheng Liu, Qiang-Jin Wu, Hong‐Hui Zhuang, Jin‐Shun Huang,

Tópico(s)

Covalent Organic Framework Applications

Resumo

The three-dimensional microporous [Cu2Mo2O8(4,4'-bpy)]n.3nH2O 1 contains (CuMo2O8N) double helical chains, which are built up from (CuIIO4N) square pyramids linked by (MoVIO4) tetrahedra and further connected to each other by 4,4'-bpy coordinated (CuIIO5N); the study of the physical properties of 1 demonstrates it is a paramagnetic semiconductor and a zeolite material; the specific channeling cavities in 1 have potential adsorption activities, indicating that 1 might be an attractive functional microporous solid material.

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