New catalysts for the oxidative polymerization of 2,6‐dimethylphenol, 3. Copper(I) cluster complexes
1977; Wiley; Volume: 178; Issue: 1 Linguagem: Inglês
10.1002/macp.1977.021780110
ISSN0025-116X
AutoresTamotsu Yoshimura, W. Storck, Georg Manecke,
Tópico(s)Polyoxometalates: Synthesis and Applications
ResumoAbstract The catalytic activities of various copper(I) clusters in the oxidation of 2,6‐dimethylphenol (XOH) in pyridine and the preparative oxidative polymerization of XOH with these complexes were investigated. It was found that the copper(I) cluster containing 1,2‐dicyano‐1,2‐ethenedithiolate ligands is more effective in the oxidative polymerization of XOH than the complex containing isomeric ligands. The electric conductivities of these Cu(I) complexes are small.
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