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Novel efficient green electroluminescent conjugated polymers based on fluorene and triarylpyrazoline for light-emitting diodes

2004; Royal Society of Chemistry; Volume: 14; Issue: 3 Linguagem: Inglês

10.1039/b313160b

1364-5501

Qiang Peng, Zhiyun Lu, Yan Huang, Minggui Xie, Dan Xiao, Shaohu Han, Junbiao Peng, Yong Cao,

Conducting polymers and applications

A series of novel light-emitting conjugated polymers based on fluorene and triarylpyrazoline were synthesized in good yields through Suzuki coupling reactions. The resulting polymers were characterized by NMR, FT-IR, elemental analysis, DSC, TGA and GPC. These polymers possess excellent thermal stability with glass transition temperatures (Tg) of 80–162 °C and onset decomposition temperatures (Td) of 376–387 °C. Cyclic voltammetry studies revealed that these polymers have good hole and electron transporting properties with LUMO energy levels of −2.97 to −2.98 eV and HOMO energy levels of −5.71 to −5.81 eV. All the polymers emit green fluorescence with very high photoluminescence (PL) quantum yields of 45–59%. Polymer light-emitting diodes (PLEDs) with the configuration ITO/PEDOT/polymer/Ba/Al were fabricated. All these devices showed bright green emission peaking at 494–500 nm with high maximum external quantum efficiencies of 0.6–2.53% and low turn-on bias voltages. The good light-emitting properties indicate that these polymers are new and promising candidates for electroluminescent materials that can be used to fabricate efficient polymer light-emitting diodes.