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The Role of Dissociative Electron Attachment in Focused Electron Beam Induced Processing: A Case Study on Cobalt Tricarbonyl Nitrosyl

2011; Wiley; Volume: 50; Issue: 40 Linguagem: Inglês

10.1002/anie.201103234

1521-3773

Sarah Engmann, Michal Staňo, Štefan Matejčík, Oddur Ingólfsson,

Ion-surface interactions and analysis

Angewandte Chemie International EditionVolume 50, Issue 40 p. 9475-9477 Communication The Role of Dissociative Electron Attachment in Focused Electron Beam Induced Processing: A Case Study on Cobalt Tricarbonyl Nitrosyl† Sarah Engmann, Sarah Engmann Science Institute and Department of Chemistry, University of Iceland, Dunhagi 3, 107 Reykjavík (Iceland)Search for more papers by this authorDr. Michal Stano, Dr. Michal Stano Department of Plasma Physics, Comenius University, Mlynska dolina F2, 84248 Bratislava (Slovakia)Search for more papers by this authorProf. Dr. Štefan Matejčík, Corresponding Author Prof. Dr. Štefan Matejčík stefan.matejcik@fmph.uniba.sk Department of Plasma Physics, Comenius University, Mlynska dolina F2, 84248 Bratislava (Slovakia) Štefan Matejčík, Department of Plasma Physics, Comenius University, Mlynska dolina F2, 84248 Bratislava (Slovakia) Oddur Ingólfsson, Science Institute and Department of Chemistry, University of Iceland, Dunhagi 3, 107 Reykjavík (Iceland)Search for more papers by this authorProf. Dr. Oddur Ingólfsson, Corresponding Author Prof. Dr. Oddur Ingólfsson odduring@hi.is Science Institute and Department of Chemistry, University of Iceland, Dunhagi 3, 107 Reykjavík (Iceland) Štefan Matejčík, Department of Plasma Physics, Comenius University, Mlynska dolina F2, 84248 Bratislava (Slovakia) Oddur Ingólfsson, Science Institute and Department of Chemistry, University of Iceland, Dunhagi 3, 107 Reykjavík (Iceland)Search for more papers by this author Sarah Engmann, Sarah Engmann Science Institute and Department of Chemistry, University of Iceland, Dunhagi 3, 107 Reykjavík (Iceland)Search for more papers by this authorDr. Michal Stano, Dr. Michal Stano Department of Plasma Physics, Comenius University, Mlynska dolina F2, 84248 Bratislava (Slovakia)Search for more papers by this authorProf. Dr. Štefan Matejčík, Corresponding Author Prof. Dr. Štefan Matejčík stefan.matejcik@fmph.uniba.sk Department of Plasma Physics, Comenius University, Mlynska dolina F2, 84248 Bratislava (Slovakia) Štefan Matejčík, Department of Plasma Physics, Comenius University, Mlynska dolina F2, 84248 Bratislava (Slovakia) Oddur Ingólfsson, Science Institute and Department of Chemistry, University of Iceland, Dunhagi 3, 107 Reykjavík (Iceland)Search for more papers by this authorProf. Dr. Oddur Ingólfsson, Corresponding Author Prof. Dr. Oddur Ingólfsson odduring@hi.is Science Institute and Department of Chemistry, University of Iceland, Dunhagi 3, 107 Reykjavík (Iceland) Štefan Matejčík, Department of Plasma Physics, Comenius University, Mlynska dolina F2, 84248 Bratislava (Slovakia) Oddur Ingólfsson, Science Institute and Department of Chemistry, University of Iceland, Dunhagi 3, 107 Reykjavík (Iceland)Search for more papers by this author First published: 25 August 2011 https://doi.org/10.1002/anie.201103234Citations: 49 † This work was supported by the Icelandic Centre for Research (RANNIS) and the Slovak grants (VEGA 1/0558/09 and APVV-0365-07). S.E. acknowledges a PhD grant from the University of Iceland and a travel grant from the COST Action (grant number CM0601, ECCL). We thank P. Klüpfel for help with the fitting procedures. Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinked InRedditWechat Abstract Put a number on it: Absolute cross-sections for dissociative electron attachment (DEA) to the common precursor molecule cobalt tricarbonyl nitrosyl in the gas phase are reported (see scheme, Co dark blue, O red, C gray, N light blue) along with the branching ratios for the negative ions and the electron affinities for the neutral radical fragments. Further, a general mechanism of DEA is proposed for metal–carbonyl compounds. Citing Literature Supporting Information Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Filename Description anie_201103234_sm_miscellaneous_information.pdf162.4 KB miscellaneous_information Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article. Volume50, Issue40September 26, 2011Pages 9475-9477 RelatedInformation