Ligand-centred reactivity in diiminepyridine complexes
2006; Royal Society of Chemistry; Issue: 46 Linguagem: Inglês
10.1039/b612251e
ISSN1477-9234
AutoresQ. Knijnenburg, Sandro Gambarotta, Peter H. M. Budzelaar,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoThe diiminepyridine ligand, made famous by Brookhart and Gibson a decade ago through its use in the first iron-containing olefin polymerization catalyst, also displays an amazing variety of ligand-centred reactions, including electron transfer, alkylation, dimerization and deprotonation. The present Perspective summarizes these reactions and also speculates on the links between ligand- and metal-centred reactivity.
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