Two Ferromagnetic One-Dimensional Nickel(II) Complexes Containing the Diamagnetic [Ni(CN)4]2− Group
2002; Wiley; Volume: 2002; Issue: 3 Linguagem: Inglês
10.1002/1099-0682(200203)2002
ISSN1099-0682
AutoresHui‐Zhong Kou, Shu‐Feng Si, Song Gao, Dai‐Zheng Liao, Zong‐Hui Jiang, Shi‐Ping Yan, Yuguo Fan, Geng‐Lin Wang,
Tópico(s)Metal complexes synthesis and properties
ResumoEuropean Journal of Inorganic ChemistryVolume 2002, Issue 3 p. 699-702 Full Paper Two Ferromagnetic One-Dimensional Nickel(II) Complexes Containing the Diamagnetic [Ni(CN)4]2− Group Hui-Zhong Kou, Hui-Zhong Kou coord@nankai.edu.cn Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorShu-Feng Si, Shu-Feng Si Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorSong Gao, Song Gao State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, P. R. ChinaSearch for more papers by this authorDai-Zheng Liao, Dai-Zheng Liao Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorZong-Hui Jiang, Zong-Hui Jiang Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorShi-Ping Yan, Shi-Ping Yan Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorYu-Guo Fan, Yu-Guo Fan Laboratory of Supramolecular Structure and spectroscopy, Jilin University, Changchun 130023, P.R. ChinaSearch for more papers by this authorGeng-Lin Wang, Geng-Lin Wang Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this author Hui-Zhong Kou, Hui-Zhong Kou coord@nankai.edu.cn Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorShu-Feng Si, Shu-Feng Si Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorSong Gao, Song Gao State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, P. R. ChinaSearch for more papers by this authorDai-Zheng Liao, Dai-Zheng Liao Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorZong-Hui Jiang, Zong-Hui Jiang Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorShi-Ping Yan, Shi-Ping Yan Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this authorYu-Guo Fan, Yu-Guo Fan Laboratory of Supramolecular Structure and spectroscopy, Jilin University, Changchun 130023, P.R. ChinaSearch for more papers by this authorGeng-Lin Wang, Geng-Lin Wang Department of Chemistry, Nankai University, Tianjin 300071, P.R. ChinaSearch for more papers by this author First published: 04 February 2002 https://doi.org/10.1002/1099-0682(200203)2002:3 3.0.CO;2-SCitations: 24Read the full textAboutPDF ToolsRequest permissionExport citationAdd to favoritesTrack citation ShareShare Give accessShare full text accessShare full-text accessPlease review our Terms and Conditions of Use and check box below to share full-text version of article.I have read and accept the Wiley Online Library Terms and Conditions of UseShareable LinkUse the link below to share a full-text version of this article with your friends and colleagues. Learn more.Copy URL Share a linkShare onFacebookTwitterLinkedInRedditWechat Abstract A cyano-bridged nickel(II) compound, [NiL][Ni(CN)4]·4H2O (L = 3,10-diethyl-1,3,5,8,10,12-hexaazacyclotetradecane), was prepared and characterized. Single crystal X-ray analysis reveals that the compound assumes a cyano-bridged chain structure in which one nickel(II) ion is coordinated by four cyanide ligands and the other is coordinated by four nitrogen atoms of the macrocyclic ligand and two nitrogen atoms of the bridging cyanide ligands. The six-coordinate nickel(II) centres display an axially elongated octahedron, whereas the four-coordinate nickel(II) centres assume planar geometry. Magnetic investigations on [NiL][Ni(CN)4]·4H2O and a similar chain-like compound [Ni(TIM)][Ni(CN)4] show the presence of weak intrachain ferromagnetic interactions between the paramagnetic nickel(II) ions through the diamagnetic [Ni(CN)4]2− anions. Citing Literature Volume2002, Issue3March 2002Pages 699-702 RelatedInformation
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