Porphyrin-based porous organic polymer-supported iron(III) catalyst for efficient aerobic oxidation of 5-hydroxymethyl-furfural into 2,5-furandicarboxylic acid
2013; Elsevier BV; Volume: 299; Linguagem: Inglês
10.1016/j.jcat.2012.12.024
ISSN1090-2694
AutoresBasudeb Saha, Dinesh Gupta, Mahdi M. Abu‐Omar, Arindam Modak, Asim Bhaumik,
Tópico(s)Supercapacitor Materials and Fabrication
ResumoEnvironmentally friendly and efficient synthesis of 2,5-furandicarboxylic acid (FDCA), a polyester building block chemical from biomass, was carried out in water by aerobic oxidation of 5-hydroxymethylfurfural (HMF) with highly cross-linked, robust structured, and thermally stable FeIII–porous organic polymer (FeIII–POP-1) material containing basic porphyrin subunits and iron metal center. EPR analysis confirmed that the catalyst retained the oxidation state of Fe(III) after catalysis and can be reused.
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