HIGH RESOLUTION RAMAN SPECTROSCOPY OF GASES: III. RAMAN SPECTRUM OF NITROGEN
1954; NRC Research Press; Volume: 32; Issue: 10 Linguagem: Inglês
10.1139/p54-066
ISSN1208-6045
Autores Tópico(s)Molecular Spectroscopy and Structure
ResumoThe pure rotational spectrum and the Q branch of the 1–0 band of N 2 were photographed in the second order of a 21 ft. grating. An analysis of the rotational spectrum yields the rotational constants[Formula: see text]The value of B 0 together with the B ν values obtained from the electronic bands of N 2 gives[Formula: see text]Revised values of the vibrational constants have also been calculated using the results of the present work and the published data on the electronic spectra.
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