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Hypersensitive radical probe studies of Gif oxidations

1996; Elsevier BV; Volume: 37; Issue: 6 Linguagem: Inglês

10.1016/0040-4039(95)02330-5

1873-3581

Martin Newcomb, Pavel A. Simakov, Seung-Un Park,

Porphyrin and Phthalocyanine Chemistry

Hypersensitive probes were employed in mechanistic studies of Gif oxidations. The results indicate that, unlike the case in enzyme catalyzed hydroxylation reactions, diffusively free radicals are formed in Gif oxidations of these substrates.