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Generation of diamondoid hydrocarbons as confined compounds in SAPO-34 catalyst in the conversion of methanol

2012; Royal Society of Chemistry; Volume: 48; Issue: 25 Linguagem: Inglês

10.1039/c2cc17676a

1364-548X

Yingxu Wei, Jinzhe Li, Cuiyu Yuan, Shutao Xu, You Zhou, Jingrun Chen, Quanyi Wang, Qing Zhang, Zhongmin Liu,

Catalytic Processes in Materials Science

Formation of adamantane hydrocarbons and their confinement in SAPO-34 caused the long induction period and the quick catalyst deactivation in methanol conversion. Via ship-in-a-bottle synthesis, adamantane and methyladamantanes could be produced from methanol conversion in the cage of 8-ring SAPO catalysts under very mild reaction conditions.