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Synthesis of chiral cyclophanes based on meta-terphenyl and pyridyl blocks

2001; Elsevier BV; Volume: 57; Issue: 48 Linguagem: Inglês

10.1016/s0040-4020(01)00966-8

1464-5416

Perumal Rajakumar, Muthialu Srisailas,

Molecular spectroscopy and chirality

Coupling of m-terphenyl dibromide with binol afforded the corresponding optically active cyclophane. Chiral cyclophanes were also obtained by the coupling of p-nitrophenol or 4,4″-bis(bromomethyl)-1,3-dibenzylbenzene with binol.