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Versatile Pyrrole Synthesis through Ruthenium(II)-Catalyzed Alkene C–H Bond Functionalization on Enamines

2012; American Chemical Society; Volume: 15; Issue: 1 Linguagem: Inglês

10.1021/ol303224e

1523-7060

Lianhui Wang, Lutz Ackermann,

Synthesis and Catalytic Reactions

An efficient ruthenium(II) catalyst enabled broadly applicable oxidative alkyne annulations with electron-rich enamines to provide diversely decorated pyrroles, even in an aerobic fashion with air as the ideal oxidant.