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BIBTEX RIS

Decarbonylative Radical Cyclization of α-Amino Selenoesters upon Electrophilic Alkenes. A General Method for the 6-Azabicyclo[3.2.1]octane Synthesis

2002; American Chemical Society; Volume: 67; Issue: 7 Linguagem: Inglês

10.1021/jo0163849

ISSN

1520-6904

Autores

Josefina Quirante, Xavier Vilà, Carmen Escolano, Josep Bonjoch,

Tópico(s)

Catalytic C–H Functionalization Methods

Resumo

alpha-Amino selenoester-tethered electronically poor alkenes on treatment with tributyltin hydride or TTMSS undergo intramolecular radical cyclization to provide 6-azabicyclo[3.2.1]octanes through 1-aminomethyl radical intermediates.

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