Absorption spectra of noble metal atoms isolated in molecular matrices
1979; Elsevier BV; Volume: 60; Issue: 2 Linguagem: Inglês
10.1016/0009-2614(79)80016-0
ISSN1873-4448
AutoresHitoshi Abe, W. Schulze, D.M. Kolb,
Tópico(s)Gas Sensing Nanomaterials and Sensors
ResumoAbstract Absorption spectra for Cu, Ag and Au atoms isolated in H 2 , D 2 , N 2 and CH 4 matrices are shown and the matrix influence on these spectra is evaluated. Unlike the inert gases, these matrices cause an unusually large crystal field splitting of the metal atom n P 3 2 level. Distinct differences in the spectra for isolation in H 2 and D 2 are found and discussed.
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