Regioselectivity in the addition of carbon nucleophiles to 1-fluoro and 1,1-difluoro π-allylpalladium complexes
1995; Elsevier BV; Volume: 36; Issue: 35 Linguagem: Inglês
10.1016/0040-4039(95)01278-p
ISSN1873-3581
AutoresGuoqiang Shi, Xianhai Huang, Fangjiang Zhang,
Tópico(s)Catalytic C–H Functionalization Methods
ResumoAttack on 1-fluoro and 1,1-difluoro π-allylpalladium complexes by stabilized carbon nucleophiles occurs preferentially at the nonfluorinated terminus, wheras the attack of a nonstabilized carbon nucleophile takes place at the fluorinated end.
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