Recent Advances in the Design and Coordination Chemistry of Heteroscorpionate Ligands Bearing Stereogenic Centres
2008; Wiley; Volume: 2008; Issue: 34 Linguagem: Inglês
10.1002/ejic.200800710
ISSN1099-0682
AutoresAntonío Otero, Juan Fernández‐Baeza, Agustín Lara‐Sánchez, Juan Tejeda, Luis F. Sánchez‐Barba,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoAbstract This review concerns the recent studies carried out by our research group and others aimed at the design of heteroscorpionate ligands based on bis(pyrazol‐1‐yl)methane‐containing stereogenic centres. The capability of these systems to stabilize chiral complexes from early to late transition metals, through their behaviour as multidentate hybrid ligands, is also described.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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