Vapour pressures and activity coefficients of (acetonitrile + water) at 308.15 K
1987; Elsevier BV; Volume: 19; Issue: 11 Linguagem: Inglês
10.1016/0021-9614(87)90053-x
ISSN1096-3626
Autores Tópico(s)Phase Equilibria and Thermodynamics
ResumoVapour pressures for {xCH3CN + (1−x)H2O} were measured over the whole composition range at 308.15 K using the static method. The results were used to calculate the activity coefficients and the excess molar Gibbs free energies. Activity coefficients and excess molar Gibbs free energies were obtained for 278.15, 288.15, 298.15, and 318.15 K using excess partial molar enthalpies reported by Stokes.
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