Ruthenium Induced C−N Bond Activation of an N-Heterocyclic Carbene: Isolation of C- and N-Bound Tautomers
2006; American Chemical Society; Volume: 128; Issue: 42 Linguagem: Inglês
10.1021/ja065582k
ISSN1943-2984
AutoresS. Burling, Mary F. Mahon, Rachael E. Powell, Michael K. Whittlesey, Jonathan M. J. Williams,
Tópico(s)Synthetic Organic Chemistry Methods
ResumoC−N bond activation of the N-heterocyclic carbene 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene occurs with Ru(PPh3)3(CO)HCl to give the C-2 bound 1-isopropyl-4,5-dimethylimidazol-2-ylidene complex Ru(C−IiPrHMe2)(PPh3)2(CO)HCl via loss of propene. In the presence of free carbene, this undergoes tautomerism to the corresponding imidazole compound Ru(N−IiPrHMe2)(PPh3)2(CO)HCl.
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