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Synthesized cellulose/succinic anhydride as an ion exchanger. Calorimetry of divalent cations in aqueous suspension

2011; Elsevier BV; Volume: 524; Issue: 1-2 Linguagem: Inglês

10.1016/j.tca.2011.06.007

1872-762X

Júlio C.P. de Melo, Edson C. Silva-Filho, Sirlane Aparecida Abreu Santana, Cláudio Airoldi,

Carbohydrate Chemistry and Synthesis

A synthetic route to a biopolymer/anhydride ion exchanger adds cellulose directly to molten succinic anhydride in a quasi solvent-free procedure. An amount of 3.07 ± 0.05 mmol of pendant groups incorporated onto the polymeric structure, which was characterized by elemental analysis, solid state carbon NMR, infrared, X-ray and thermogravimetry. The new polysaccharide is able to exchange cations from aqueous solution through a batchwise methodology, to obtain 2.46 ± 0.09 mmol g−1 for divalent cobalt and nickel cations. The net thermal effects obtained from calorimetric titrations gave endothermic values of 3.81 ± 0.02 and 2.35 ± 0.01 kJ mol−1. The spontaneity of this ion-exchange process reflected in negative Gibbs energies and also a positive entropic contribution. These thermodynamic data at the solid/liquid interface suggests a favorable ion exchange process for this anchored biopolymer, for cation removal from the environment.