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Fluorine takes a hike: remarkable room-temperature rearrangement of the C1 isomer of C60F36 into the C3 isomer via a 1,3-fluorine shift

2002; Royal Society of Chemistry; Issue: 22 Linguagem: Inglês

10.1039/b208670k

1364-548X

Anthony G. Avent, Roger Taylor,

Graphene research and applications

In a toluene/CDCl3 solution at room temperature, the C1 isomer of C60F36 rearranges into the C3 isomer over a period of four days, as a result of a unique 1,3-shift of fluorine; this rare example of addend migration across a fullerene cage surface is accelerated by air.